Zimbabwe, under the guidance of Kaitano Tembo, will take on Nigeria in the semi-final of the tournament at The Valley as preparations continue for the 2027 Africa Cup of Nations qualifiers later this year.
Munetsi linked up with the squad in Birmingham on Friday as the Warriors began camp for the invitational competition, which will also feature Jamaica and India.
The experienced midfielder believes the tournament presents an important opportunity for the team to build chemistry, especially with several new faces included in the squad.
"We have some big games coming up, the first one is against Nigeria, which everyone is looking forward to," Munetsi told the Warriors media as quoted by Daily Post Nigeria.
"We have some new guys coming in, some fresh faces. It's a good opportunity for us to know each other. Obviously, these two games are important but the one we are looking forward to is the AFCON qualifiers that are coming up."
The former Orlando Pirates midfielder has become one of Zimbabwe's key senior figures in recent years and is expected to play a leading role as the Warriors aim to build momentum ahead of the continental qualifiers.
The Proteas Women will travel to Bulawayo in September for a historic first-ever T20 International series against Zimbabwe Women, with the neighbouring nations set to contest five matches at Queens Sports Club.
Nigeria international Terem Moffi has admitted that he remains uncertain over his club future following the end of his loan spell with Portuguese giants FC Porto.
Kaitano Tembo says he is proud to lead Zimbabwe at the upcoming Unity Cup to be held at the Valley Stadium in London.
Belgian giants Anderlecht have reportedly renewed their interest in Zimbabwe international Tawanda Maswanhise following his impressive season with Motherwell.
