The former Tottenham Hotspur man has been typically prolific since making the move to the German giants, bagging an astonishing 82 goals in 91 games played across all competitions since joining Bayern.
He added another one to the tally in the Bavarians' 4-0 win over Hoffenheim on Saturday afternoon to bring his total league goals for this season to 26, five ahead of the nearest competitors Patrick Schick of Bayer Leverkusen and Borussia Dortmund's Serhou Guirassy, who both ended the season on 21 goals.
Michael Olise opened the scoring for Bayern in the 33rd minute, with Joshua Kimmich doubling their advantage eight minutes into the second half.
Serge Gnabry added a third in the 80th minute before Kane came on to add the cherry on the cake of a successful season for Bayern in the 86th minute.
Elsewhere in the Bundesliga on Saturday, which saw a full round of fixtures as the final matchday of the season, Werder Bremen hammered Heidenheim 4-1 while Wolfsburg were able to sneak by Borussia Monchengladbach 1-0.
Augsburg went down 1-2 at home against Union Berlin, with Dortmund battering 10-man Holstein Kiel 3-0, with Guirassy getting on the scoresheet via the penalty spot.
VfB Stuttgart prevailed 3-2 over RB Leipzig in a five-goal thriller at the Red Bull Aren, awhile Eintracht Frankfurt showed their class in a comfortable 3-1 win over SC Freiburg.
Mainz and Bayer Leverkusen played out a thrilling 2-2 draw and VfL Bochum ran out 2-0 winners away from home against St Pauli.
Borussia Dortmund and Hamburger SV were the big winners in a dramatic Bundesliga round, as Dortmund beat TSG Hoffenheim 2-0 at the Westfalenstadion and Hamburg edged SV Werder Bremen 3-2 in a Nordderby at the Volksparkstadion.
Saturday proved to be a goal-fest in the Bundesliga as the top two sides in the standings blew away their opposition to pull further away from the rest.
VfB Stuttgart will aim to maintain their strong home record when they host Bundesliga leaders Bayern Munich this weekend.
Aleix Garcia is enjoying the best spell of his career, turning himself into a key figure in Bayer Leverkusen's midfield and pushing for a place in Spain's 2026 World Cup squad.
